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生物質(zhì)熱解氣化發(fā)電設(shè)備

發(fā)布時(shí)間:2023-04-21 發(fā)布人:中拓 發(fā)布來(lái)源:http://www.ptvydps.cn/
生物質(zhì)氣化是指將生物質(zhì)燃料轉(zhuǎn)化為可燃性氣體的熱化學(xué)過(guò)程。在這個(gè)過(guò)程中水蒸氣游離氧或結(jié)合氧與燃料中的碳進(jìn)行熱化學(xué)反應(yīng),生成可燃?xì)怏w。 生物質(zhì)氣化過(guò)程比較復(fù)雜,氣化反應(yīng)條件也各不相同但所有氣化反應(yīng)的過(guò)程基本都包括生物質(zhì)的干燥熱解氧化和還原反應(yīng)過(guò)程。
Biomass gasification refers to the thermochemical process of converting biomass fuel into combustible gas. During this process, water vapor undergoes a thermochemical reaction between free oxygen or combined oxygen and carbon in the fuel, generating combustible gases& nbsp; The biomass gasification process is relatively complex, and the gasification reaction conditions are also different. However, all gasification reactions basically include the drying, pyrolysis, oxidation, and reduction reactions of biomass.
下吸式固定床氣化爐,其特征是氣體和生物質(zhì)的運(yùn)動(dòng)方向相同,所以又稱順氣式氣化爐。下吸式固定床氣化爐的熱解產(chǎn)物必須通過(guò)制熱的氧化層,因此揮發(fā)分中的焦油可以得到充分的分解,燃?xì)庵械慕褂秃看蟠蟮陀谏衔焦潭ù矚饣癄t。它適用于相對(duì)干燥的塊狀物料(含水率低于30%),以及含有少量粗糙顆粒的混合物料,且運(yùn)行方便可靠。由于下吸式固定床氣化爐的燃?xì)庵薪褂秃枯^低,特別適用于小型發(fā)電系統(tǒng)。
The downdraft fixed bed gasifier is characterized by the same movement direction of gas and biomass, so it is also known as a downstream gasifier. The pyrolysis products of the downdraft fixed bed gasifier must pass through the heated oxide layer, so the tar in the volatile matter can be fully decomposed, and the tar content in the gas is much lower than that of the updraft fixed bed gasifier. It is suitable for relatively dry block materials (with a moisture content below 30%), as well as mixed materials containing a small amount of rough particles, and is easy and reliable to operate. Due to the low tar content in the gas of the downdraft fixed bed gasifier, it is particularly suitable for small power generation systems.
干燥層
Drying layer
氣化爐上層為干燥區(qū),從上面加入的物料直接進(jìn)入到干燥區(qū),物料在這里同下面三個(gè)反應(yīng)區(qū)生成的熱氣體產(chǎn)物進(jìn)行換熱,使原料中的水分蒸發(fā)出去,該層溫度為 200~300℃。干燥層的產(chǎn)物為干物料和水蒸氣,水蒸氣隨著下面的三個(gè)反應(yīng)區(qū)的產(chǎn)熱排出氣化爐,而干物料則落入熱解區(qū)。
The upper layer of the gasifier is a drying zone, where the materials added directly enter the drying zone. Here, the materials exchange heat with the hot gas products generated in the three reaction zones below, allowing the moisture in the raw materials to evaporate. The temperature of this layer is; 200~300℃。 The products of the drying layer are dry materials and water vapor, which are discharged from the gasifier with the heat generation in the three reaction zones below, while the dry materials fall into the pyrolysis zone.
熱解氣發(fā)電機(jī)組
熱解層
pyrolytic layer
生物干物料向下運(yùn)行進(jìn)入熱解層,同時(shí)將生物質(zhì)加熱,當(dāng)生物質(zhì)受熱后發(fā)生熱解反應(yīng)。通過(guò)熱解反應(yīng)生物質(zhì)中大部分的揮發(fā)分從固體中分離出去,在500~600℃時(shí)基本完成,剩下木炭。熱解區(qū)的主要產(chǎn)物為炭氫氣水蒸氣一氧化碳二氧化碳甲烷焦油及其他烴類(lèi)物質(zhì)等。
The biological dry material moves downwards into the pyrolysis layer, while heating the biomass. When the biomass is heated, a pyrolysis reaction occurs. Most of the volatile components in biomass are separated from the solid through pyrolysis reaction, and are basically completed at 500-600 ℃, leaving charcoal. The main products of the pyrolysis zone are carbon, hydrogen, water vapor, carbon monoxide, carbon dioxide, methane, tar, and other hydrocarbon substances.
氧化層
oxide layer
熱解的剩余木炭與被的空氣發(fā)生劇烈反應(yīng),釋放大量熱量。由于是限氧燃燒,氧氣的供給是不充分的,因而不完全燃燒反應(yīng)同時(shí)發(fā)生,生成一氧化碳,同時(shí)也放熱量。在氧化區(qū),溫度可達(dá)1000℃,反應(yīng)方程式為:
The remaining charcoal from pyrolysis reacts violently with the air, releasing a large amount of heat. Due to limited oxygen combustion, the supply of oxygen is insufficient, resulting in incomplete combustion reactions occurring simultaneously, generating carbon monoxide and also releasing heat. In the oxidation zone, the temperature can reach 1000 ℃, and the reaction equation is:
△H △H=408.8千焦
△H  △ H=408.8 kJ
在氧化區(qū)進(jìn)行的均為燃燒反應(yīng),并放出熱量,也正是這部分反應(yīng)熱為還原區(qū)的還原反應(yīng)物料的裂解和干燥,提供了熱源。在氧化區(qū)中生成的熱氣體(一氧化碳和二氧化碳)進(jìn)入氣化爐的還原區(qū),灰分落入下部的灰室中。
The reactions carried out in the oxidation zone are all combustion reactions and release heat, which provides a heat source for the cracking and drying of the reduction reaction materials in the reduction zone. The hot gases generated in the oxidation zone (carbon monoxide and carbon dioxide) enter the reduction zone of the gasifier, and the ash falls into the lower ash chamber.
還原層
Restoring layer
在還原區(qū)已沒(méi)有氧氣存在,在氧化反應(yīng)中生成的二氧化碳在這里同炭及水蒸氣發(fā)生還原反應(yīng),生成一氧化碳(CO)和氫氣(H2)。由于還原反應(yīng)是吸熱反應(yīng),還原區(qū)的溫度也相應(yīng)降低,約為600~800℃。還原區(qū)的主要產(chǎn)物為一氧化碳(CO)二氧化碳(CO2)和氫氣(H2)。
There is no oxygen present in the reduction zone, and the carbon dioxide generated during the oxidation reaction undergoes a reduction reaction with carbon and water vapor, producing carbon monoxide (CO) and hydrogen gas (H2). Since the reduction reaction is a endothermic reaction, the temperature of the reduction zone also decreases correspondingly, about 600~800 ℃. The main products of the reduction zone are carbon monoxide (CO), carbon dioxide (CO2), and hydrogen gas (H2).
氣化實(shí)際上總是兼有燃料的干燥裂解過(guò)程。在實(shí)際的操作過(guò)程中,上述四個(gè)區(qū)域沒(méi)有明確的邊界,是相互滲透和交錯(cuò)的。所以在氣化爐出口,產(chǎn)出氣體成分主要為一氧化碳(CO),二氧化碳(CO2)氫氣(H2)甲烷(CH4)焦油及少量共他烴類(lèi),還有水蒸氣及少量灰分。
Gasification actually always involves the drying and cracking process of fuel. In the actual operation process, the four regions mentioned above do not have clear boundaries and are mutually penetrating and intersecting. So at the outlet of the gasifier, the main gas components produced are carbon monoxide (CO), carbon dioxide (CO2), hydrogen (H2), methane (CH4), tar, and a small amount of co hydrocarbons, as well as water vapor and a small amount of ash.

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